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Nitrilium betaines

Term · Chemistry · MLC-T-CHM-007959

A class of 1,3-dipolar compounds that are resonance-stabilized zwitterionic species with a formal positive charge on a nitrogen atom and a negative charge on an adjacent atom. These compounds contain a C≡N+ bond and an adjacent negatively charged atom, such as oxygen, nitrogen, or carbon. They are reactive intermediates that participate in cycloaddition reactions, leading to the formation of heterocyclic rings.

Table 1. Record
IdentifierMLC-T-CHM-007959
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1351 (https://doi.org/10.1351/pac199567081307)
See alsoDipolar compounds; Nitrile imides; Nitrile oxides; Nitrile sulfides; Nitrile ylides; Nitriles
Record as JSON
{
  "id": "MLC-T-CHM-007959",
  "term": "Nitrilium betaines",
  "field": "Chemistry",
  "definition": "A class of 1,3-dipolar compounds that are resonance-stabilized zwitterionic species with a formal positive charge on a nitrogen atom and a negative charge on an adjacent atom. These compounds contain a C≡N+ bond and an adjacent negatively charged atom, such as oxygen, nitrogen, or carbon. They are reactive intermediates that participate in cycloaddition reactions, leading to the formation of heterocyclic rings.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "dipolar compounds",
    "nitrile imides",
    "nitrile oxides",
    "nitrile sulfides",
    "nitrile ylides",
    "nitriles"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1351 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/nitrilium-betaines/"
}

Record 8,448 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.