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Non-vertical energy transfer

Term · Chemistry · MLC-T-CHM-008061

An energy transfer process with a small Franck-Condon factor, because the donor or the acceptor has an excited-state equilibrium geometry strongly displaced from its ground-state geometry. The transfer therefore requires nuclear rearrangement and is slower than vertical transfer, in which both partners keep nearly the same geometry in the two states.

Table 1. Record
IdentifierMLC-T-CHM-008061
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 374 (https://doi.org/10.1351/pac200779030293)
See alsoFranck-Condon principle
Record as JSON
{
  "id": "MLC-T-CHM-008061",
  "term": "Non-vertical energy transfer",
  "field": "Chemistry",
  "definition": "An energy transfer process with a small Franck-Condon factor, because the donor or the acceptor has an excited-state equilibrium geometry strongly displaced from its ground-state geometry. The transfer therefore requires nuclear rearrangement and is slower than vertical transfer, in which both partners keep nearly the same geometry in the two states.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "Franck-Condon principle"
  ],
  "references": [
    "PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 374 (https://doi.org/10.1351/pac200779030293)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/non-vertical-energy-transfer/"
}

Record 8,556 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.