MLchartDataset catalogue

Osones

Term · Chemistry · MLC-T-CHM-008355

An obsolescent name for 1,2-dicarbonyl sugar derivatives (1,2-ketoaldoses) with an aldehyde group at C-1 and a ketone group at C-2. Osones are usually prepared by hydrolysis of osazones, the sugar bis(phenylhydrazones), so they are products rather than intermediates of osazone formation. Reduction of an osone gives the 2-ketose, for example D-glucosone gives D-fructose.

Table 1. Record
IdentifierMLC-T-CHM-008355
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1354 (https://doi.org/10.1351/pac199567081307); White Book, 2nd ed., p. 132 (https://iupac.qmul.ac.uk/bibliog/white.html)
See alsoHydrolysis; Ketoaldoses; Osazones
Record as JSON
{
  "id": "MLC-T-CHM-008355",
  "term": "Osones",
  "field": "Chemistry",
  "definition": "An obsolescent name for 1,2-dicarbonyl sugar derivatives (1,2-ketoaldoses) with an aldehyde group at C-1 and a ketone group at C-2. Osones are usually prepared by hydrolysis of osazones, the sugar bis(phenylhydrazones), so they are products rather than intermediates of osazone formation. Reduction of an osone gives the 2-ketose, for example D-glucosone gives D-fructose.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "hydrolysis",
    "ketoaldoses",
    "osazones"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1354 (https://doi.org/10.1351/pac199567081307)",
    "White Book, 2nd ed., p. 132 (https://iupac.qmul.ac.uk/bibliog/white.html)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/osones/"
}

Record 8,878 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.