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Oxonium ylides

Term · Chemistry · MLC-T-CHM-008406

Dipolar chemical species in which a negatively charged carbon atom (a carbanion) is directly attached to a positively charged trivalent oxygen atom (an oxonium center). These are 1,2-dipolar species with the general structure R2O+-C-R'2. Oxonium ylides are highly reactive intermediates and are isomeric with the corresponding ethers.

Table 1. Record
IdentifierMLC-T-CHM-008406
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1355 (https://doi.org/10.1351/pac199567081307)
See alsoCarbonyl imides; Carbonyl oxides; Carbonyl ylides; Dipolar compounds; Ylides
Record as JSON
{
  "id": "MLC-T-CHM-008406",
  "term": "Oxonium ylides",
  "field": "Chemistry",
  "definition": "Dipolar chemical species in which a negatively charged carbon atom (a carbanion) is directly attached to a positively charged trivalent oxygen atom (an oxonium center). These are 1,2-dipolar species with the general structure R2O+-C-R'2. Oxonium ylides are highly reactive intermediates and are isomeric with the corresponding ethers.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "carbonyl imides",
    "carbonyl oxides",
    "carbonyl ylides",
    "dipolar compounds",
    "ylides"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1355 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/oxonium-ylides/"
}

Record 8,931 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.