MLchartDataset catalogue

Partial isotopic scrambling

Term · Chemistry · MLC-T-CHM-008487

The incomplete redistribution of isotopes within a molecule or ion during a chemical reaction or fragmentation process, leading to a non-statistical distribution of isotopic labels. This phenomenon provides insights into reaction mechanisms and the connectivity of atoms within a molecular structure. It is often observed in mass spectrometry experiments.

Table 1. Record
IdentifierMLC-T-CHM-008487
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 2013, 85, 1515. 'Definitions of terms relating to mass spectrometry (IUPAC Recommendations 2013)' on page 1574 (https://doi.org/10.1351/PAC-REC-06-04-06)
Record as JSON
{
  "id": "MLC-T-CHM-008487",
  "term": "Partial isotopic scrambling",
  "field": "Chemistry",
  "definition": "The incomplete redistribution of isotopes within a molecule or ion during a chemical reaction or fragmentation process, leading to a non-statistical distribution of isotopic labels. This phenomenon provides insights into reaction mechanisms and the connectivity of atoms within a molecular structure. It is often observed in mass spectrometry experiments.",
  "subject": "Analytical Chemistry",
  "references": [
    "PAC, 2013, 85, 1515. 'Definitions of terms relating to mass spectrometry (IUPAC Recommendations 2013)' on page 1574 (https://doi.org/10.1351/PAC-REC-06-04-06)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/partial-isotopic-scrambling/"
}

Record 9,015 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.