MLchartDataset catalogue

Ion pair return

Term · Chemistry · MLC-T-CHM-006091

A process in which an ion pair, formed as an intermediate in a chemical reaction, reverts to the starting covalent reactant. This can occur before the ions fully dissociate or react with other species. It is often observed in solvolysis reactions and can lead to racemization or isotopic scrambling.

Table 1. Record
IdentifierMLC-T-CHM-006091
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1127 (https://doi.org/10.1351/pac199466051077)
See alsoChiral; Geminate recombination; Ionization; Racemization; Ion pair; Molecularity
Record as JSON
{
  "id": "MLC-T-CHM-006091",
  "term": "Ion pair return",
  "field": "Chemistry",
  "definition": "A process in which an ion pair, formed as an intermediate in a chemical reaction, reverts to the starting covalent reactant. This can occur before the ions fully dissociate or react with other species. It is often observed in solvolysis reactions and can lead to racemization or isotopic scrambling.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "chiral",
    "geminate recombination",
    "ionization",
    "racemization",
    "ion pair",
    "molecularity"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1127 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/ion-pair-return/"
}

Record 6,462 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.