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Ion pair

Term · Chemistry · MLC-T-CHM-006090

An association between a cation and an anion in solution, held together by electrostatic forces, without forming a covalent bond. These pairs can be solvent-separated, where solvent molecules are interspersed between the ions, or contact ion pairs, where the ions are directly adjacent. Ion pairs influence reaction rates and equilibria in many chemical processes.

Table 1. Record
IdentifierMLC-T-CHM-006090
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1126 (https://doi.org/10.1351/pac199466051077); PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1344 (https://doi.org/10.1351/pac199567081307)
See alsoCommon-ion effect; Constituent; Coulomb; Covalent bond; Dissociation; Ion pair return; Isotopic labelling; Relative permittivity; Special salt effect
Record as JSON
{
  "id": "MLC-T-CHM-006090",
  "term": "Ion pair",
  "field": "Chemistry",
  "definition": "An association between a cation and an anion in solution, held together by electrostatic forces, without forming a covalent bond. These pairs can be solvent-separated, where solvent molecules are interspersed between the ions, or contact ion pairs, where the ions are directly adjacent. Ion pairs influence reaction rates and equilibria in many chemical processes.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "common-ion effect",
    "constituent",
    "coulomb",
    "covalent bond",
    "dissociation",
    "ion pair return",
    "isotopic labelling",
    "relative permittivity",
    "special salt effect"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1126 (https://doi.org/10.1351/pac199466051077)",
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1344 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/ion-pair/"
}

Record 6,461 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.