Common-ion effect
Term · Chemistry · MLC-T-CHM-002282
The decrease in the solubility of an ionic precipitate or the degree of dissociation of a weak electrolyte when a soluble salt containing a common ion is added to the solution. This effect is a direct consequence of Le Chatelier's principle, shifting the equilibrium to reduce the concentration of the common ion. For example, adding sodium acetate to a solution of acetic acid will suppress the dissociation of the acid.
| Identifier | MLC-T-CHM-002282 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1098 (https://doi.org/10.1351/pac199466051077) |
| See also | Cation; Dissociation; Ionization; Mass-law effect; Pre-equilibrium; Quasi-equilibrium; Rate of reaction; Solvolysis; Substrate |
Record as JSON
{
"id": "MLC-T-CHM-002282",
"term": "Common-ion effect",
"field": "Chemistry",
"definition": "The decrease in the solubility of an ionic precipitate or the degree of dissociation of a weak electrolyte when a soluble salt containing a common ion is added to the solution. This effect is a direct consequence of Le Chatelier's principle, shifting the equilibrium to reduce the concentration of the common ion. For example, adding sodium acetate to a solution of acetic acid will suppress the dissociation of the acid.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"cation",
"dissociation",
"ionization",
"mass-law effect",
"pre-equilibrium",
"quasi-equilibrium",
"rate of reaction",
"solvolysis",
"substrate"
],
"references": [
"PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1098 (https://doi.org/10.1351/pac199466051077)"
],
"url": "https://mlchart.com/terminology/chemistry/common-ion-effect/"
}
Record 2,435 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.