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Ion-pair formation

Term · Chemistry · MLC-T-CHM-006144

An ionization event in mass spectrometry in which one molecule yields both a cationic and an anionic fragment, so ions of each polarity appear among the products. In solution chemistry the same words describe the association of a free cation and anion into a single unit held by Coulombic attraction, which lowers the free-ion concentration and so the conductivity of the solution.

Table 1. Record
IdentifierMLC-T-CHM-006144
FieldChemistry
SubjectPhysical and Biophysical Chemistry
ReferencesPAC, 1991, 63, 1541. 'Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)' on page 1548 (https://doi.org/10.1351/pac199163101541)
See alsoIonization
Record as JSON
{
  "id": "MLC-T-CHM-006144",
  "term": "Ion-pair formation",
  "field": "Chemistry",
  "definition": "An ionization event in mass spectrometry in which one molecule yields both a cationic and an anionic fragment, so ions of each polarity appear among the products. In solution chemistry the same words describe the association of a free cation and anion into a single unit held by Coulombic attraction, which lowers the free-ion concentration and so the conductivity of the solution.",
  "subject": "Physical and Biophysical Chemistry",
  "see_also": [
    "ionization"
  ],
  "references": [
    "PAC, 1991, 63, 1541. 'Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)' on page 1548 (https://doi.org/10.1351/pac199163101541)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/ion-pair-formation/"
}

Record 6,518 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.