Partition coefficient
Term · Chemistry · MLC-T-CHM-008519
The ratio of the concentration of a solute in one phase to its concentration in a second, immiscible phase at equilibrium. This value, often denoted as P or K_D, indicates the relative affinity of a compound for each phase. It is a fundamental parameter in chromatography and solvent extraction, influencing separation efficiency.
| Identifier | MLC-T-CHM-008519 |
|---|---|
| Field | Chemistry |
| Subject | Analytical Chemistry |
| References | PAC, 1993, 65, 2373. 'Nomenclature for liquid-liquid distribution (solvent extraction) (IUPAC Recommendations 1993)' on page 2385 (https://doi.org/10.1351/pac199365112373); PAC, 1996, 68, 957. 'Glossary of terms in quantities and units in Clinical Chemistry (IUPAC-IFCC Recommendations 1996)' on page 986 (https://doi.org/10.1351/pac199668040957) |
| See also | Distribution ratio; Partition constant; Partition ratio |
Record as JSON
{
"id": "MLC-T-CHM-008519",
"term": "Partition coefficient",
"field": "Chemistry",
"definition": "The ratio of the concentration of a solute in one phase to its concentration in a second, immiscible phase at equilibrium. This value, often denoted as P or K_D, indicates the relative affinity of a compound for each phase. It is a fundamental parameter in chromatography and solvent extraction, influencing separation efficiency.",
"subject": "Analytical Chemistry",
"see_also": [
"distribution ratio",
"partition constant",
"partition ratio"
],
"references": [
"PAC, 1993, 65, 2373. 'Nomenclature for liquid-liquid distribution (solvent extraction) (IUPAC Recommendations 1993)' on page 2385 (https://doi.org/10.1351/pac199365112373)",
"PAC, 1996, 68, 957. 'Glossary of terms in quantities and units in Clinical Chemistry (IUPAC-IFCC Recommendations 1996)' on page 986 (https://doi.org/10.1351/pac199668040957)"
],
"url": "https://mlchart.com/terminology/chemistry/partition-coefficient/"
}
Record 9,052 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.