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Photodetachment

Term · Chemistry · MLC-T-CHM-008844

The loss of an electron by an anion that has absorbed a photon, which leaves behind a neutral atom or molecule. The photon energy must exceed the electron affinity of that neutral species, so the threshold energy gives the electron affinity. Removing an electron from a neutral species to give a cation is called photoionization instead.

Table 1. Record
IdentifierMLC-T-CHM-008844
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2260 (https://doi.org/10.1351/pac199668122223)
See alsoPhotoexcitation
Record as JSON
{
  "id": "MLC-T-CHM-008844",
  "term": "Photodetachment",
  "field": "Chemistry",
  "definition": "The loss of an electron by an anion that has absorbed a photon, which leaves behind a neutral atom or molecule. The photon energy must exceed the electron affinity of that neutral species, so the threshold energy gives the electron affinity. Removing an electron from a neutral species to give a cation is called photoionization instead.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "photoexcitation"
  ],
  "references": [
    "PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2260 (https://doi.org/10.1351/pac199668122223)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/photodetachment/"
}

Record 9,392 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.