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Phototautomerisation

Term · Chemistry · MLC-T-CHM-008932

A light-induced interconversion between two tautomeric forms of a molecule. This process involves the migration of a hydrogen atom or proton, accompanied by a rearrangement of double bonds, which is triggered by the absorption of a photon. Phototautomerisation can lead to changes in the spectroscopic properties, reactivity, or biological activity of the molecule, and is often observed in heterocyclic compounds.

Table 1. Record
IdentifierMLC-T-CHM-008932
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 400 (https://doi.org/10.1351/pac200779030293)
Record as JSON
{
  "id": "MLC-T-CHM-008932",
  "term": "Phototautomerisation",
  "field": "Chemistry",
  "definition": "A light-induced interconversion between two tautomeric forms of a molecule. This process involves the migration of a hydrogen atom or proton, accompanied by a rearrangement of double bonds, which is triggered by the absorption of a photon. Phototautomerisation can lead to changes in the spectroscopic properties, reactivity, or biological activity of the molecule, and is often observed in heterocyclic compounds.",
  "subject": "Organic and Biomolecular Chemistry",
  "references": [
    "PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 400 (https://doi.org/10.1351/pac200779030293)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/phototautomerisation/"
}

Record 9,487 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.