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Q-e scheme

Term · Chemistry · MLC-T-CHM-009714

A semi-empirical model used to predict the monomer reactivity ratios in radical copolymerization. The 'Q' parameter represents the resonance stabilization of the monomer and its radical, while 'e' describes the polarity of the monomer and its radical. This scheme provides a framework for understanding and predicting the composition of copolymers formed from different monomer pairs.

Table 1. Record
IdentifierMLC-T-CHM-009714
FieldChemistry
SubjectPolymer
SynonymsAlfrey-Price scheme
ReferencesPAC, 2008, 80, 2163. 'Glossary of terms related to kinetics, thermodynamics, and mechanisms of polymerization (IUPAC Recommendations 2008)' on page 2182 (https://doi.org/10.1351/pac200880102163)
See alsoBinary copolymerisation; Monomer reactivity ratios
Record as JSON
{
  "id": "MLC-T-CHM-009714",
  "term": "Q-e scheme",
  "field": "Chemistry",
  "definition": "A semi-empirical model used to predict the monomer reactivity ratios in radical copolymerization. The 'Q' parameter represents the resonance stabilization of the monomer and its radical, while 'e' describes the polarity of the monomer and its radical. This scheme provides a framework for understanding and predicting the composition of copolymers formed from different monomer pairs.",
  "synonyms": [
    "Alfrey-Price scheme"
  ],
  "subject": "Polymer",
  "see_also": [
    "binary copolymerisation",
    "monomer reactivity ratios"
  ],
  "references": [
    "PAC, 2008, 80, 2163. 'Glossary of terms related to kinetics, thermodynamics, and mechanisms of polymerization (IUPAC Recommendations 2008)' on page 2182 (https://doi.org/10.1351/pac200880102163)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/q-e-scheme/"
}

Record 10,321 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.