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Quasi-molecular ion

Term · Chemistry · MLC-T-CHM-013460

An ion of mass close to that of the intact molecule in a soft ionization spectrum, either a protonated molecule, MH+, or an ion that has lost one hydrogen atom from a molecular ion, (M-H)+. It is seen in chemical ionization, electrospray and similar techniques where a true molecular ion is weak or absent. In the strict IUPAC sense it covers only these two kinds, so adduct ions such as ammonium or sodium attachments are excluded.

Table 1. Record
IdentifierMLC-T-CHM-013460
FieldChemistry
SubjectPhysical and Biophysical Chemistry
ReferencesPAC, 1991, 63, 1541. 'Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)' on page 1550 (https://doi.org/10.1351/pac199163101541)
Record as JSON
{
  "id": "MLC-T-CHM-013460",
  "term": "Quasi-molecular ion",
  "field": "Chemistry",
  "definition": "An ion of mass close to that of the intact molecule in a soft ionization spectrum, either a protonated molecule, MH+, or an ion that has lost one hydrogen atom from a molecular ion, (M-H)+. It is seen in chemical ionization, electrospray and similar techniques where a true molecular ion is weak or absent. In the strict IUPAC sense it covers only these two kinds, so adduct ions such as ammonium or sodium attachments are excluded.",
  "subject": "Physical and Biophysical Chemistry",
  "references": [
    "PAC, 1991, 63, 1541. 'Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)' on page 1550 (https://doi.org/10.1351/pac199163101541)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/quasi-molecular-ion/"
}

Record 10,385 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.