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Reissert compounds

Term · Chemistry · MLC-T-CHM-013492

Compounds formed by adding an acyl group to the ring nitrogen and a cyano group to the adjacent carbon of quinoline, isoquinoline and related nitrogen heterocycles, as in 1-acyl-1,2-dihydroquinoline-2-carbonitriles. They are made by treating the heterocycle with an acid chloride and a cyanide source. Acid hydrolysis of the quinoline adduct gives quinaldic acid together with the aldehyde corresponding to the acyl group.

Table 1. Record
IdentifierMLC-T-CHM-013492
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1363 (https://doi.org/10.1351/pac199567081307)
Record as JSON
{
  "id": "MLC-T-CHM-013492",
  "term": "Reissert compounds",
  "field": "Chemistry",
  "definition": "Compounds formed by adding an acyl group to the ring nitrogen and a cyano group to the adjacent carbon of quinoline, isoquinoline and related nitrogen heterocycles, as in 1-acyl-1,2-dihydroquinoline-2-carbonitriles. They are made by treating the heterocycle with an acid chloride and a cyanide source. Acid hydrolysis of the quinoline adduct gives quinaldic acid together with the aldehyde corresponding to the acyl group.",
  "subject": "Organic and Biomolecular Chemistry",
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1363 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/reissert-compounds/"
}

Record 10,772 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.