Thioanhydrides
Term · Chemistry · MLC-T-CHM-012009
Compounds of the type acyl-S-acyl, in which a sulfur atom replaces the bridging oxygen of a carboxylic anhydride, also called diacyl sulfides or diacylsulfanes. One or both acyl groups may themselves be thioacyl groups. They act as acylating agents, analogous to anhydrides, and release a thiocarboxylic acid when they transfer an acyl group.
| Identifier | MLC-T-CHM-012009 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| Synonyms | acid thioanhydrides; diacylsulfanes |
| References | PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1372 (https://doi.org/10.1351/pac199567081307) |
| See also | Acyl groups |
Record as JSON
{
"id": "MLC-T-CHM-012009",
"term": "Thioanhydrides",
"field": "Chemistry",
"definition": "Compounds of the type acyl-S-acyl, in which a sulfur atom replaces the bridging oxygen of a carboxylic anhydride, also called diacyl sulfides or diacylsulfanes. One or both acyl groups may themselves be thioacyl groups. They act as acylating agents, analogous to anhydrides, and release a thiocarboxylic acid when they transfer an acyl group.",
"synonyms": [
"acid thioanhydrides",
"diacylsulfanes"
],
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"acyl groups"
],
"references": [
"PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1372 (https://doi.org/10.1351/pac199567081307)"
],
"url": "https://mlchart.com/terminology/chemistry/thioanhydrides/"
}
Record 12,808 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.