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Ribbon delocalisation

Term · Chemistry · MLC-T-CHM-013509

A specific type of electron delocalization occurring in certain conjugated systems, where the delocalized electrons are confined to a narrow, ribbon-like region within the molecule. This phenomenon is observed in molecules with extended pi-electron systems, such as polyenes or polycyclic aromatic hydrocarbons. It influences the electronic properties and reactivity of these compounds, often leading to distinct spectroscopic characteristics.

Table 1. Record
IdentifierMLC-T-CHM-013509
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1999, 71, 1919. 'Glossary of terms used in theoretical organic chemistry' on page 1961 (https://doi.org/10.1351/pac199971101919)
See alsoDelocalization
Record as JSON
{
  "id": "MLC-T-CHM-013509",
  "term": "Ribbon delocalisation",
  "field": "Chemistry",
  "definition": "A specific type of electron delocalization occurring in certain conjugated systems, where the delocalized electrons are confined to a narrow, ribbon-like region within the molecule. This phenomenon is observed in molecules with extended pi-electron systems, such as polyenes or polycyclic aromatic hydrocarbons. It influences the electronic properties and reactivity of these compounds, often leading to distinct spectroscopic characteristics.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "delocalization"
  ],
  "references": [
    "PAC, 1999, 71, 1919. 'Glossary of terms used in theoretical organic chemistry' on page 1961 (https://doi.org/10.1351/pac199971101919)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/ribbon-delocalisation/"
}

Record 11,003 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.