Delocalization of electrons
Term · Chemistry · MLC-T-CHM-002977
The phenomenon where electrons are not confined to a single atom or bond but are distributed over multiple atoms or across an extended region within a molecule or material. This allows for enhanced electronic conductivity and unique optical properties in conjugated polymers. The extent of delocalization influences the band gap and absorption characteristics.
| Identifier | MLC-T-CHM-002977 |
|---|---|
| Field | Chemistry |
| Subject | Polymer |
| References | PAC, 2022, 94, 15. 'Glossary of terms relating to electronic, photonic and magnetic properties of polymers (IUPAC Recommendations 2021)' on page 22 (https://doi.org/10.1515/pac-2020-0501) |
| See also | Antisoliton; Conjugated polymer; Extent of electron delocalization; Lattice; Molecular orbital theory; Polysilanes |
Record as JSON
{
"id": "MLC-T-CHM-002977",
"term": "Delocalization of electrons",
"field": "Chemistry",
"definition": "The phenomenon where electrons are not confined to a single atom or bond but are distributed over multiple atoms or across an extended region within a molecule or material. This allows for enhanced electronic conductivity and unique optical properties in conjugated polymers. The extent of delocalization influences the band gap and absorption characteristics.",
"subject": "Polymer",
"see_also": [
"antisoliton",
"conjugated polymer",
"extent of electron delocalization",
"lattice",
"molecular orbital theory",
"polysilanes"
],
"references": [
"PAC, 2022, 94, 15. 'Glossary of terms relating to electronic, photonic and magnetic properties of polymers (IUPAC Recommendations 2021)' on page 22 (https://doi.org/10.1515/pac-2020-0501)"
],
"url": "https://mlchart.com/terminology/chemistry/delocalization-of-electrons/"
}
Record 3,168 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.