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Root-mean-square unperturbed end-to-end distance

Term · Chemistry · MLC-T-CHM-010408

The average spatial separation between the ends of a polymer chain in an ideal theta solvent, where polymer-solvent and polymer-polymer interactions are balanced, and long-range excluded volume effects are absent. This value represents the intrinsic dimensions of the polymer chain, reflecting only short-range interactions and bond geometry. It is a fundamental property for characterizing polymer chain stiffness.

Table 1. Record
IdentifierMLC-T-CHM-010408
FieldChemistry
SubjectPolymer
ReferencesPAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 76 (https://doi.org/10.1515/pac-2013-0201)
Record as JSON
{
  "id": "MLC-T-CHM-010408",
  "term": "Root-mean-square unperturbed end-to-end distance",
  "field": "Chemistry",
  "definition": "The average spatial separation between the ends of a polymer chain in an ideal theta solvent, where polymer-solvent and polymer-polymer interactions are balanced, and long-range excluded volume effects are absent. This value represents the intrinsic dimensions of the polymer chain, reflecting only short-range interactions and bond geometry. It is a fundamental property for characterizing polymer chain stiffness.",
  "subject": "Polymer",
  "references": [
    "PAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 76 (https://doi.org/10.1515/pac-2013-0201)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/root-mean-square-unperturbed-end-to-end-distance/"
}

Record 11,071 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.