Mean-square unperturbed end-to-end distance
Term · Chemistry · MLC-T-CHM-007087
The average of the square of the distance between the ends of a polymer chain in a theta solvent, where polymer-solvent and polymer-polymer interactions effectively cancel out. This value represents the intrinsic size of the polymer chain in the absence of long-range excluded volume effects. It is a characteristic property of the polymer chain architecture.
| Identifier | MLC-T-CHM-007087 |
|---|---|
| Field | Chemistry |
| Subject | Polymer |
| References | PAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 76 (https://doi.org/10.1515/pac-2013-0201) |
| See also | Effective bond length; Rotational isomeric state |
Record as JSON
{
"id": "MLC-T-CHM-007087",
"term": "Mean-square unperturbed end-to-end distance",
"field": "Chemistry",
"definition": "The average of the square of the distance between the ends of a polymer chain in a theta solvent, where polymer-solvent and polymer-polymer interactions effectively cancel out. This value represents the intrinsic size of the polymer chain in the absence of long-range excluded volume effects. It is a characteristic property of the polymer chain architecture.",
"subject": "Polymer",
"see_also": [
"effective bond length",
"rotational isomeric state"
],
"references": [
"PAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 76 (https://doi.org/10.1515/pac-2013-0201)"
],
"url": "https://mlchart.com/terminology/chemistry/mean-square-unperturbed-end-to-end-distance/"
}
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