Unperturbed conformational state
Term · Chemistry · MLC-T-CHM-012446
The average conformation of a polymer chain in a theta solvent, where long-range interactions between segments of the chain are effectively screened. In this state, the polymer chain behaves as an ideal random coil, and its dimensions are determined solely by short-range interactions and bond rotations. This state is achieved at the theta temperature.
| Identifier | MLC-T-CHM-012446 |
|---|---|
| Field | Chemistry |
| Subject | Polymer |
| References | PAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 74 (https://doi.org/10.1515/pac-2013-0201) |
Record as JSON
{
"id": "MLC-T-CHM-012446",
"term": "Unperturbed conformational state",
"field": "Chemistry",
"definition": "The average conformation of a polymer chain in a theta solvent, where long-range interactions between segments of the chain are effectively screened. In this state, the polymer chain behaves as an ideal random coil, and its dimensions are determined solely by short-range interactions and bond rotations. This state is achieved at the theta temperature.",
"subject": "Polymer",
"references": [
"PAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 74 (https://doi.org/10.1515/pac-2013-0201)"
],
"url": "https://mlchart.com/terminology/chemistry/unperturbed-conformational-state/"
}
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