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Sacrificial donor

Term · Chemistry · MLC-T-CHM-010473

A molecular entity that supplies the electron in a photoinduced electron transfer and is then destroyed by an irreversible chemical reaction, so it is never regenerated. Its consumption blocks back electron transfer, letting the reduced product of the partner accumulate. Triethanolamine, EDTA and methanol are typical sacrificial donors in photocatalytic hydrogen evolution.

Table 1. Record
IdentifierMLC-T-CHM-010473
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2272 (https://doi.org/10.1351/pac199668122223)
See alsoElectron donor; Photoinduced electron transfer
Record as JSON
{
  "id": "MLC-T-CHM-010473",
  "term": "Sacrificial donor",
  "field": "Chemistry",
  "definition": "A molecular entity that supplies the electron in a photoinduced electron transfer and is then destroyed by an irreversible chemical reaction, so it is never regenerated. Its consumption blocks back electron transfer, letting the reduced product of the partner accumulate. Triethanolamine, EDTA and methanol are typical sacrificial donors in photocatalytic hydrogen evolution.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "electron donor",
    "photoinduced electron transfer"
  ],
  "references": [
    "PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2272 (https://doi.org/10.1351/pac199668122223)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/sacrificial-donor/"
}

Record 11,139 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.