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Sacrificial acceptor

Term · Chemistry · MLC-T-CHM-010472

A molecular entity that takes up the electron in a photoinduced electron transfer and is then destroyed by an irreversible chemical reaction, so it is never regenerated. Its consumption blocks back electron transfer, letting the oxidized product of the partner accumulate. Persulfate, silver(I) and iodate are typical sacrificial acceptors in photocatalytic water oxidation to oxygen.

Table 1. Record
IdentifierMLC-T-CHM-010472
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2272 (https://doi.org/10.1351/pac199668122223)
See alsoElectron acceptor; Oxidation; Photoinduced electron transfer
Record as JSON
{
  "id": "MLC-T-CHM-010472",
  "term": "Sacrificial acceptor",
  "field": "Chemistry",
  "definition": "A molecular entity that takes up the electron in a photoinduced electron transfer and is then destroyed by an irreversible chemical reaction, so it is never regenerated. Its consumption blocks back electron transfer, letting the oxidized product of the partner accumulate. Persulfate, silver(I) and iodate are typical sacrificial acceptors in photocatalytic water oxidation to oxygen.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "electron acceptor",
    "oxidation",
    "photoinduced electron transfer"
  ],
  "references": [
    "PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2272 (https://doi.org/10.1351/pac199668122223)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/sacrificial-acceptor/"
}

Record 11,138 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.