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Singlet-triplet energy transfer

Term · Chemistry · MLC-T-CHM-010908

The transfer of excitation energy from an excited singlet donor to an acceptor that ends up in an excited triplet state. Because a singlet donor and a singlet acceptor have zero total spin while the final state includes a triplet, the process breaks the spin conservation rule and is normally very slow, although heavy atoms can enable it through spin-orbit coupling. The spin-allowed alternatives are singlet-singlet and triplet-triplet transfer.

Table 1. Record
IdentifierMLC-T-CHM-010908
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2273 (https://doi.org/10.1351/pac199668122223)
See alsoEnergy transfer; Singlet state; Spin conservation rule; Triplet state
Record as JSON
{
  "id": "MLC-T-CHM-010908",
  "term": "Singlet-triplet energy transfer",
  "field": "Chemistry",
  "definition": "The transfer of excitation energy from an excited singlet donor to an acceptor that ends up in an excited triplet state. Because a singlet donor and a singlet acceptor have zero total spin while the final state includes a triplet, the process breaks the spin conservation rule and is normally very slow, although heavy atoms can enable it through spin-orbit coupling. The spin-allowed alternatives are singlet-singlet and triplet-triplet transfer.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "energy transfer",
    "singlet state",
    "spin conservation rule",
    "triplet state"
  ],
  "references": [
    "PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2273 (https://doi.org/10.1351/pac199668122223)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/singlet-triplet-energy-transfer/"
}

Record 11,618 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.