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Spin-orbit coupling

Term · Chemistry · MLC-T-CHM-011219

The interaction between the intrinsic angular momentum (spin) of an electron and its orbital angular momentum. This interaction leads to a splitting of energy levels and can facilitate intersystem crossing, a process where a molecule transitions between states of different spin multiplicity. Its magnitude increases significantly with the atomic number of the elements involved.

Table 1. Record
IdentifierMLC-T-CHM-011219
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2277 (https://doi.org/10.1351/pac199668122223)
See alsoChemical induction; Spin-orbit splitting
Record as JSON
{
  "id": "MLC-T-CHM-011219",
  "term": "Spin-orbit coupling",
  "field": "Chemistry",
  "definition": "The interaction between the intrinsic angular momentum (spin) of an electron and its orbital angular momentum. This interaction leads to a splitting of energy levels and can facilitate intersystem crossing, a process where a molecule transitions between states of different spin multiplicity. Its magnitude increases significantly with the atomic number of the elements involved.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "chemical induction",
    "spin-orbit splitting"
  ],
  "references": [
    "PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2277 (https://doi.org/10.1351/pac199668122223)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/spin-orbit-coupling/"
}

Record 11,955 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.