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Stereoelectronic

Term · Chemistry · MLC-T-CHM-011372

Relating to the interplay between the spatial arrangement of atoms (steric factors) and the electronic properties of a molecule, particularly how these factors influence chemical reactivity and molecular conformation. This concept considers the orientation of orbitals and electron density in determining reaction pathways and molecular stability. It often involves analyzing orbital overlap and hyperconjugation effects.

Table 1. Record
IdentifierMLC-T-CHM-011372
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2218 (https://doi.org/10.1351/pac199668122193)
See alsoElectronic state; Ground state; Molecular entity; Transition state
Record as JSON
{
  "id": "MLC-T-CHM-011372",
  "term": "Stereoelectronic",
  "field": "Chemistry",
  "definition": "Relating to the interplay between the spatial arrangement of atoms (steric factors) and the electronic properties of a molecule, particularly how these factors influence chemical reactivity and molecular conformation. This concept considers the orientation of orbitals and electron density in determining reaction pathways and molecular stability. It often involves analyzing orbital overlap and hyperconjugation effects.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "electronic state",
    "ground state",
    "molecular entity",
    "transition state"
  ],
  "references": [
    "PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2218 (https://doi.org/10.1351/pac199668122193)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/stereoelectronic/"
}

Record 12,111 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.