Steric factor
Term · Chemistry · MLC-T-CHM-011392
A parameter in collision theory that accounts for the orientation of molecules during a collision, influencing the probability of a reaction occurring. It represents the fraction of collisions that have the correct spatial arrangement for bond breaking and formation. This factor typically ranges from 0 to 1, with values less than 1 indicating that not all collisions lead to a reaction.
| Identifier | MLC-T-CHM-011392 |
|---|---|
| Field | Chemistry |
| Subject | Physical and Biophysical Chemistry |
| References | PAC, 1996, 68, 149. 'A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)' on page 187 (https://doi.org/10.1351/pac199668010149); Purple Book, 1st ed., p. 50 (http://old.iupac.org/publications/books/author/metanomski.html) |
| See also | Collision frequency; Collision theory; Reaction probability; Chain length; Freely rotating chain; Root-mean-square end-to-end distance |
Record as JSON
{
"id": "MLC-T-CHM-011392",
"term": "Steric factor",
"field": "Chemistry",
"definition": "A parameter in collision theory that accounts for the orientation of molecules during a collision, influencing the probability of a reaction occurring. It represents the fraction of collisions that have the correct spatial arrangement for bond breaking and formation. This factor typically ranges from 0 to 1, with values less than 1 indicating that not all collisions lead to a reaction.",
"subject": "Physical and Biophysical Chemistry",
"see_also": [
"collision frequency",
"collision theory",
"reaction probability",
"chain length",
"freely rotating chain",
"root-mean-square end-to-end distance"
],
"references": [
"PAC, 1996, 68, 149. 'A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)' on page 187 (https://doi.org/10.1351/pac199668010149)",
"Purple Book, 1st ed., p. 50 (http://old.iupac.org/publications/books/author/metanomski.html)"
],
"url": "https://mlchart.com/terminology/chemistry/steric-factor/"
}
Record 12,132 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.