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Steric factor

Term · Chemistry · MLC-T-CHM-011392

A parameter in collision theory that accounts for the orientation of molecules during a collision, influencing the probability of a reaction occurring. It represents the fraction of collisions that have the correct spatial arrangement for bond breaking and formation. This factor typically ranges from 0 to 1, with values less than 1 indicating that not all collisions lead to a reaction.

Table 1. Record
IdentifierMLC-T-CHM-011392
FieldChemistry
SubjectPhysical and Biophysical Chemistry
ReferencesPAC, 1996, 68, 149. 'A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)' on page 187 (https://doi.org/10.1351/pac199668010149); Purple Book, 1st ed., p. 50 (http://old.iupac.org/publications/books/author/metanomski.html)
See alsoCollision frequency; Collision theory; Reaction probability; Chain length; Freely rotating chain; Root-mean-square end-to-end distance
Record as JSON
{
  "id": "MLC-T-CHM-011392",
  "term": "Steric factor",
  "field": "Chemistry",
  "definition": "A parameter in collision theory that accounts for the orientation of molecules during a collision, influencing the probability of a reaction occurring. It represents the fraction of collisions that have the correct spatial arrangement for bond breaking and formation. This factor typically ranges from 0 to 1, with values less than 1 indicating that not all collisions lead to a reaction.",
  "subject": "Physical and Biophysical Chemistry",
  "see_also": [
    "collision frequency",
    "collision theory",
    "reaction probability",
    "chain length",
    "freely rotating chain",
    "root-mean-square end-to-end distance"
  ],
  "references": [
    "PAC, 1996, 68, 149. 'A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)' on page 187 (https://doi.org/10.1351/pac199668010149)",
    "Purple Book, 1st ed., p. 50 (http://old.iupac.org/publications/books/author/metanomski.html)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/steric-factor/"
}

Record 12,132 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.