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Sultims

Term · Chemistry · MLC-T-CHM-011574

Tautomeric forms of sultams in which the hydrogen of the ring NH has shifted to a sulfonyl oxygen, leaving a sulfur-nitrogen double bond within the ring and a hydroxyl group on sulfur. A cyclic sulfonamide and its sultim are related in the same way as an amide and its imidic acid tautomer. The sultim form is normally much less stable than the sultam.

Table 1. Record
IdentifierMLC-T-CHM-011574
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1370 (https://doi.org/10.1351/pac199567081307)
See alsoSultams
Record as JSON
{
  "id": "MLC-T-CHM-011574",
  "term": "Sultims",
  "field": "Chemistry",
  "definition": "Tautomeric forms of sultams in which the hydrogen of the ring NH has shifted to a sulfonyl oxygen, leaving a sulfur-nitrogen double bond within the ring and a hydroxyl group on sulfur. A cyclic sulfonamide and its sultim are related in the same way as an amide and its imidic acid tautomer. The sultim form is normally much less stable than the sultam.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "sultams"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1370 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/sultims/"
}

Record 12,333 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.