Surface excess Helmholtz energy

{
  "id": "MLC-T-CHM-011647",
  "term": "Surface excess Helmholtz energy",
  "field": "Chemistry",
  "definition": "The Helmholtz energy associated with the formation of an interface, representing the work required to create a new surface at constant temperature and volume. This thermodynamic quantity is analogous to surface excess Gibbs energy but under different constraints. It is measured in joules per unit area.",
  "subject": "Physical and Biophysical Chemistry",
  "see_also": [
    "surface excess energy",
    "surface excess entropy",
    "thermodynamic temperature"
  ],
  "references": [
    "PAC, 1972, 31, 577. 'Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry' on page 599 (https://doi.org/10.1351/pac197231040577)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/surface-excess-helmholtz-energy/"
}