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Surface excess enthalpy

Term · Chemistry · MLC-T-CHM-011644

The enthalpy associated with the formation of an interface, representing the difference in enthalpy between the actual system with an interface and a hypothetical system without an interface. This quantity accounts for the energy and pressure-volume work changes at the surface. It is measured in joules per unit area.

Table 1. Record
IdentifierMLC-T-CHM-011644
FieldChemistry
SubjectPhysical and Biophysical Chemistry
ReferencesPAC, 1972, 31, 577. 'Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry' on page 599 (https://doi.org/10.1351/pac197231040577)
See alsoGibbs surface; Surface excess energy; Surface tension
Record as JSON
{
  "id": "MLC-T-CHM-011644",
  "term": "Surface excess enthalpy",
  "field": "Chemistry",
  "definition": "The enthalpy associated with the formation of an interface, representing the difference in enthalpy between the actual system with an interface and a hypothetical system without an interface. This quantity accounts for the energy and pressure-volume work changes at the surface. It is measured in joules per unit area.",
  "subject": "Physical and Biophysical Chemistry",
  "see_also": [
    "Gibbs surface",
    "surface excess energy",
    "surface tension"
  ],
  "references": [
    "PAC, 1972, 31, 577. 'Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry' on page 599 (https://doi.org/10.1351/pac197231040577)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/surface-excess-enthalpy/"
}

Record 12,409 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.