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Tropones

Term · Chemistry · MLC-T-CHM-013671

A class of non-benzenoid aromatic compounds featuring a seven-membered hydrocarbon ring containing a ketone functional group. The parent compound is tropone, or cyclohepta-2,4,6-trien-1-one, which exhibits aromatic character due to the contribution of a dipolar resonance structure with a positive charge on the ring and a negative charge on the oxygen. This charge separation gives it a large dipole moment and chemical properties distinct from those of typical aliphatic or aromatic ketones.

Table 1. Record
IdentifierMLC-T-CHM-013671
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1373 (https://doi.org/10.1351/pac199567081307)
Record as JSON
{
  "id": "MLC-T-CHM-013671",
  "term": "Tropones",
  "field": "Chemistry",
  "definition": "A class of non-benzenoid aromatic compounds featuring a seven-membered hydrocarbon ring containing a ketone functional group. The parent compound is tropone, or cyclohepta-2,4,6-trien-1-one, which exhibits aromatic character due to the contribution of a dipolar resonance structure with a positive charge on the ring and a negative charge on the oxygen. This charge separation gives it a large dipole moment and chemical properties distinct from those of typical aliphatic or aromatic ketones.",
  "subject": "Organic and Biomolecular Chemistry",
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1373 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/tropones/"
}

Record 13,140 of 13,678 in Chemistry terminology (MLC-0109). Request the full dataset.