Meisenheimer adduct
Term · Chemistry · MLC-T-CHM-007147
An anionic sigma complex formed by the nucleophilic addition of a carbanion or other nucleophile to an electron-deficient aromatic ring. The negative charge is delocalized over the ring and often stabilized by electron-withdrawing groups. These adducts are intermediates in nucleophilic aromatic substitution reactions, particularly those involving activated aromatic systems.
| Identifier | MLC-T-CHM-007147 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1138 (https://doi.org/10.1351/pac199466051077) |
| See also | Lewis adduct; Lewis base; Adduct; Aromatic; Electrophile; Ethers; Substitution reaction; Σ-adduct |
Record as JSON
{
"id": "MLC-T-CHM-007147",
"term": "Meisenheimer adduct",
"field": "Chemistry",
"definition": "An anionic sigma complex formed by the nucleophilic addition of a carbanion or other nucleophile to an electron-deficient aromatic ring. The negative charge is delocalized over the ring and often stabilized by electron-withdrawing groups. These adducts are intermediates in nucleophilic aromatic substitution reactions, particularly those involving activated aromatic systems.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"Lewis adduct",
"Lewis base",
"adduct",
"aromatic",
"electrophile",
"ethers",
"substitution reaction",
"σ-adduct"
],
"references": [
"PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1138 (https://doi.org/10.1351/pac199466051077)"
],
"url": "https://mlchart.com/terminology/chemistry/meisenheimer-adduct/"
}
Record 7,573 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.