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Photochemical nucleophile-olefin combination - aromatic substitution

Term · Chemistry · MLC-T-CHM-008821

A reaction sequence involving the light-induced combination of a nucleophile and an olefin, followed by an aromatic substitution. This process typically occurs through the formation of a radical intermediate upon photoexcitation. The overall reaction results in the functionalization of an aromatic ring with both a nucleophilic and an olefinic moiety.

Table 1. Record
IdentifierMLC-T-CHM-008821
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
Synonymsphoto-NOCAS
ReferencesPAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 385 (https://doi.org/10.1351/pac200779030293)
See alsoAromatic substitution photochemical electrophile-olefin combination; Aromatic substitution photochemical radical-olefin combination
Record as JSON
{
  "id": "MLC-T-CHM-008821",
  "term": "Photochemical nucleophile-olefin combination - aromatic substitution",
  "field": "Chemistry",
  "definition": "A reaction sequence involving the light-induced combination of a nucleophile and an olefin, followed by an aromatic substitution. This process typically occurs through the formation of a radical intermediate upon photoexcitation. The overall reaction results in the functionalization of an aromatic ring with both a nucleophilic and an olefinic moiety.",
  "synonyms": [
    "photo-NOCAS"
  ],
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "aromatic substitution photochemical electrophile-olefin combination",
    "aromatic substitution photochemical radical-olefin combination"
  ],
  "references": [
    "PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 385 (https://doi.org/10.1351/pac200779030293)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/photochemical-nucleophile-olefin-combination-aromatic-substitution/"
}

Record 9,368 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.