Aromatic substitution photochemical radical-olefin combination

{
  "id": "MLC-T-CHM-000787",
  "term": "Aromatic substitution photochemical radical-olefin combination",
  "field": "Chemistry",
  "definition": "A photochemical aromatic substitution that joins three separate partners, a free radical, an alkene and an aromatic ring, with the regiochemistry set by a photoinduced electron transfer step. It differs from the electrophile-olefin combination, a two-component reaction in which an electron-rich arene reacts with an electron-deficient olefin in a polar solvent.",
  "synonyms": [
    "photo-ROCAS"
  ],
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "aromatic substitution photochemical electrophile-olefin combination",
    "photochemical nucleophile-olefin combination - aromatic substitution"
  ],
  "references": [
    "PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 386 (https://doi.org/10.1351/pac200779030293)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/aromatic-substitution-photochemical-radical-olefin-combination/"
}