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Π-adduct

Term · Chemistry · MLC-T-CHM-008417

A species formed by the association of an electrophile or nucleophile with the pi (π) electron system of an unsaturated molecule. This interaction involves the donation or acceptance of electrons from the π-system, leading to a temporary or stable complex. Such adducts are intermediates in many organic reactions, particularly electrophilic aromatic substitution and cycloaddition reactions.

Table 1. Record
IdentifierMLC-T-CHM-008417
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
Synonymsπ-complex
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1154 (https://doi.org/10.1351/pac199466051077); PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1312 (https://doi.org/10.1351/pac199567081307)
See alsoAdduct; Complex; Coordination
Record as JSON
{
  "id": "MLC-T-CHM-008417",
  "term": "Π-adduct",
  "field": "Chemistry",
  "definition": "A species formed by the association of an electrophile or nucleophile with the pi (π) electron system of an unsaturated molecule. This interaction involves the donation or acceptance of electrons from the π-system, leading to a temporary or stable complex. Such adducts are intermediates in many organic reactions, particularly electrophilic aromatic substitution and cycloaddition reactions.",
  "synonyms": [
    "π-complex"
  ],
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "adduct",
    "complex",
    "coordination"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1154 (https://doi.org/10.1351/pac199466051077)",
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1312 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/p-adduct/"
}

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