MLchartDataset catalogue

Absolute activity

Term · Chemistry · MLC-T-CHM-000047

The exponential of a substance's chemical potential divided by the product of the gas constant and the thermodynamic temperature, written lambda = exp(mu/RT). It is a dimensionless measure of how strongly the substance tends to leave its phase. The relative activity used in equilibrium constants is the ratio of the absolute activity to its value in the chosen standard state, so it equals one in that state.

Table 1. Record
IdentifierMLC-T-CHM-000047
FieldChemistry
SubjectPhysical and Biophysical Chemistry
ReferencesGreen Book, 2nd ed., p. 40 (https://goldbook.iupac.org/files/pdf/green_book_2ed.pdf)
See alsoChemical potential; Gas constant; Thermodynamic temperature
Record as JSON
{
  "id": "MLC-T-CHM-000047",
  "term": "Absolute activity",
  "field": "Chemistry",
  "definition": "The exponential of a substance's chemical potential divided by the product of the gas constant and the thermodynamic temperature, written lambda = exp(mu/RT). It is a dimensionless measure of how strongly the substance tends to leave its phase. The relative activity used in equilibrium constants is the ratio of the absolute activity to its value in the chosen standard state, so it equals one in that state.",
  "subject": "Physical and Biophysical Chemistry",
  "see_also": [
    "chemical potential",
    "gas constant",
    "thermodynamic temperature"
  ],
  "references": [
    "Green Book, 2nd ed., p. 40 (https://goldbook.iupac.org/files/pdf/green_book_2ed.pdf)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/absolute-activity/"
}

Record 49 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.