Chain reactivation
Term · Chemistry · MLC-T-CHM-001848
The conversion of a dormant polymer chain into an active one, allowing it to resume propagation. This process is the reverse of chain deactivation and is a characteristic feature of reversible-deactivation radical polymerization. The equilibrium between active and dormant species controls the overall polymerization rate and the properties of the final polymer, such as its molar-mass distribution.
| Identifier | MLC-T-CHM-001848 |
|---|---|
| Field | Chemistry |
| Subject | Polymer |
| Synonyms | activation (in a chain polymerization); reactivation |
| References | PAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1118 (https://doi.org/10.1515/pac-2020-1211) |
| See also | Chain activation; Chain deactivation; Dormant species; Inactive chain |
Record as JSON
{
"id": "MLC-T-CHM-001848",
"term": "Chain reactivation",
"field": "Chemistry",
"definition": "The conversion of a dormant polymer chain into an active one, allowing it to resume propagation. This process is the reverse of chain deactivation and is a characteristic feature of reversible-deactivation radical polymerization. The equilibrium between active and dormant species controls the overall polymerization rate and the properties of the final polymer, such as its molar-mass distribution.",
"synonyms": [
"activation (in a chain polymerization)",
"reactivation"
],
"subject": "Polymer",
"see_also": [
"chain activation",
"chain deactivation",
"dormant species",
"inactive chain"
],
"references": [
"PAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1118 (https://doi.org/10.1515/pac-2020-1211)"
],
"url": "https://mlchart.com/terminology/chemistry/chain-reactivation/"
}
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