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Charge-transfer absorption

Term · Chemistry · MLC-T-CHM-001914

The absorption of electromagnetic radiation that results in the excitation of an electron from a donor orbital to an acceptor orbital, leading to a partial or complete transfer of charge between two molecular entities or within a single molecule. This process creates a transient excited state with a redistributed electron density. The absorption band is characteristic of the donor-acceptor interaction and often appears in the visible or ultraviolet region of the spectrum.

Table 1. Record
IdentifierMLC-T-CHM-001914
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
SynonymsCT absorption
ReferencesPAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 312 (https://doi.org/10.1351/pac200779030293)
Record as JSON
{
  "id": "MLC-T-CHM-001914",
  "term": "Charge-transfer absorption",
  "field": "Chemistry",
  "definition": "The absorption of electromagnetic radiation that results in the excitation of an electron from a donor orbital to an acceptor orbital, leading to a partial or complete transfer of charge between two molecular entities or within a single molecule. This process creates a transient excited state with a redistributed electron density. The absorption band is characteristic of the donor-acceptor interaction and often appears in the visible or ultraviolet region of the spectrum.",
  "synonyms": [
    "CT absorption"
  ],
  "subject": "Organic and Biomolecular Chemistry",
  "references": [
    "PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 312 (https://doi.org/10.1351/pac200779030293)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/charge-transfer-absorption/"
}

Record 2,053 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.