Metal to metal charge transfer transition
Term · Chemistry · MLC-T-CHM-007250
An electronic transition occurring in polymetallic complexes where an electron moves from an orbital primarily localized on one metal center to an orbital primarily localized on another metal center. This type of transition is characteristic of mixed-valence compounds. It is often responsible for intense absorption bands in the visible region of the electromagnetic spectrum.
| Identifier | MLC-T-CHM-007250 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| Synonyms | MMCT transition |
| References | PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2254 (https://doi.org/10.1351/pac199668122223) |
| See also | Electron transfer; Electronic state; Intervalence charge transfer |
Record as JSON
{
"id": "MLC-T-CHM-007250",
"term": "Metal to metal charge transfer transition",
"field": "Chemistry",
"definition": "An electronic transition occurring in polymetallic complexes where an electron moves from an orbital primarily localized on one metal center to an orbital primarily localized on another metal center. This type of transition is characteristic of mixed-valence compounds. It is often responsible for intense absorption bands in the visible region of the electromagnetic spectrum.",
"synonyms": [
"MMCT transition"
],
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"electron transfer",
"electronic state",
"intervalence charge transfer"
],
"references": [
"PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2254 (https://doi.org/10.1351/pac199668122223)"
],
"url": "https://mlchart.com/terminology/chemistry/metal-to-metal-charge-transfer-transition/"
}
Record 7,681 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.