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Ligand to metal charge transfer transition

Term · Chemistry · MLC-T-CHM-006573

An electronic transition in a coordination compound where an electron moves from an orbital primarily localized on the ligand to an orbital primarily localized on the central metal atom. This process results in a temporary decrease in the oxidation state of the metal. Such transitions are responsible for the intense colors observed in many transition metal complexes.

Table 1. Record
IdentifierMLC-T-CHM-006573
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
SynonymsLMCT transition
ReferencesPAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2252 (https://doi.org/10.1351/pac199668122223)
See alsoElectron transfer; Electronic state; Metal to ligand charge transfer transition
Record as JSON
{
  "id": "MLC-T-CHM-006573",
  "term": "Ligand to metal charge transfer transition",
  "field": "Chemistry",
  "definition": "An electronic transition in a coordination compound where an electron moves from an orbital primarily localized on the ligand to an orbital primarily localized on the central metal atom. This process results in a temporary decrease in the oxidation state of the metal. Such transitions are responsible for the intense colors observed in many transition metal complexes.",
  "synonyms": [
    "LMCT transition"
  ],
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "electron transfer",
    "electronic state",
    "metal to ligand charge transfer transition"
  ],
  "references": [
    "PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2252 (https://doi.org/10.1351/pac199668122223)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/ligand-to-metal-charge-transfer-transition/"
}

Record 6,967 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.