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Localized-itinerant transition

Term · Chemistry · MLC-T-CHM-006742

A phase transition in which the electronic states of a material change from being localized at specific atomic sites to becoming delocalized and able to move freely throughout the material. This transition is often driven by changes in temperature, pressure, or doping. It is observed in certain transition metal oxides and other strongly correlated electron systems.

Table 1. Record
IdentifierMLC-T-CHM-006742
FieldChemistry
SubjectInorganic Chemistry
ReferencesPAC, 1994, 66, 577. 'Definitions of terms relating to phase transitions of the solid state (IUPAC Recommendations 1994)' on page 585 (https://doi.org/10.1351/pac199466030577)
See alsoMott transition; Polaron
Record as JSON
{
  "id": "MLC-T-CHM-006742",
  "term": "Localized-itinerant transition",
  "field": "Chemistry",
  "definition": "A phase transition in which the electronic states of a material change from being localized at specific atomic sites to becoming delocalized and able to move freely throughout the material. This transition is often driven by changes in temperature, pressure, or doping. It is observed in certain transition metal oxides and other strongly correlated electron systems.",
  "subject": "Inorganic Chemistry",
  "see_also": [
    "Mott transition",
    "polaron"
  ],
  "references": [
    "PAC, 1994, 66, 577. 'Definitions of terms relating to phase transitions of the solid state (IUPAC Recommendations 1994)' on page 585 (https://doi.org/10.1351/pac199466030577)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/localized-itinerant-transition/"
}

Record 7,141 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.