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Charge-transfer complex

Term · Chemistry · MLC-T-CHM-001916

An adduct formed between two or more molecular entities, one acting as an electron donor and the other as an electron acceptor, where a fraction of electronic charge is transferred from the donor to the acceptor. This interaction is weaker than a covalent bond but stronger than typical van der Waals forces. These complexes often exhibit characteristic absorption bands in the visible or ultraviolet region, distinct from those of the individual components.

Table 1. Record
IdentifierMLC-T-CHM-001916
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
Synonymselectron-donor-acceptor complex
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1094 (https://doi.org/10.1351/pac199466051077); PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1328 (https://doi.org/10.1351/pac199567081307)
See alsoExcited state; Moiety
Record as JSON
{
  "id": "MLC-T-CHM-001916",
  "term": "Charge-transfer complex",
  "field": "Chemistry",
  "definition": "An adduct formed between two or more molecular entities, one acting as an electron donor and the other as an electron acceptor, where a fraction of electronic charge is transferred from the donor to the acceptor. This interaction is weaker than a covalent bond but stronger than typical van der Waals forces. These complexes often exhibit characteristic absorption bands in the visible or ultraviolet region, distinct from those of the individual components.",
  "synonyms": [
    "electron-donor-acceptor complex"
  ],
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "excited state",
    "moiety"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1094 (https://doi.org/10.1351/pac199466051077)",
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1328 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/charge-transfer-complex/"
}

Record 2,055 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.