MLchartDataset catalogue

Charged residue model

Term · Chemistry · MLC-T-CHM-001909

A model describing the formation of gas-phase ions from charged droplets in electrospray ionization. As solvent evaporates, the droplet shrinks and its surface charge density increases until it divides, a process that repeats until a single analyte ion remains in a very small droplet. The final gas-phase ion is formed when the last of the solvent evaporates, which contrasts with the ion evaporation model where ions are ejected directly from the droplet surface.

Table 1. Record
IdentifierMLC-T-CHM-001909
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 2013, 85, 1515. 'Definitions of terms relating to mass spectrometry (IUPAC Recommendations 2013)' on page 1528 (https://doi.org/10.1351/PAC-REC-06-04-06)
See alsoIon evaporation model
Record as JSON
{
  "id": "MLC-T-CHM-001909",
  "term": "Charged residue model",
  "field": "Chemistry",
  "definition": "A model describing the formation of gas-phase ions from charged droplets in electrospray ionization. As solvent evaporates, the droplet shrinks and its surface charge density increases until it divides, a process that repeats until a single analyte ion remains in a very small droplet. The final gas-phase ion is formed when the last of the solvent evaporates, which contrasts with the ion evaporation model where ions are ejected directly from the droplet surface.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "ion evaporation model"
  ],
  "references": [
    "PAC, 2013, 85, 1515. 'Definitions of terms relating to mass spectrometry (IUPAC Recommendations 2013)' on page 1528 (https://doi.org/10.1351/PAC-REC-06-04-06)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/charged-residue-model/"
}

Record 2,046 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.