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Cyclohexadienyl cations

Term · Chemistry · MLC-T-CHM-002823

Carbocations derived from cyclohexadiene, characterized by a delocalized positive charge over a six-membered ring containing two double bonds and a sp2 hybridized carbon atom. These species are also known as arenium ions when they are intermediates in electrophilic aromatic substitution reactions. The positive charge is delocalized across five carbon atoms of the ring.

Table 1. Record
IdentifierMLC-T-CHM-002823
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1330 (https://doi.org/10.1351/pac199567081307)
See alsoArenium ions
Record as JSON
{
  "id": "MLC-T-CHM-002823",
  "term": "Cyclohexadienyl cations",
  "field": "Chemistry",
  "definition": "Carbocations derived from cyclohexadiene, characterized by a delocalized positive charge over a six-membered ring containing two double bonds and a sp2 hybridized carbon atom. These species are also known as arenium ions when they are intermediates in electrophilic aromatic substitution reactions. The positive charge is delocalized across five carbon atoms of the ring.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "arenium ions"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1330 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/cyclohexadienyl-cations/"
}

Record 2,997 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.