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Dehydrobenzenes

Term · Chemistry · MLC-T-CHM-002959

Reactive intermediates of formula C6H4 derived from benzene by formally removing two hydrogen atoms, named as didehydrobenzenes with locants. The 1,2-isomer is benzyne, with a formal triple bond, while 1,3- and 1,4-didehydrobenzene are separate species with no such bond, the latter being the intermediate of the Bergman cyclization. All are generated in situ and are too reactive to isolate under ordinary conditions.

Table 1. Record
IdentifierMLC-T-CHM-002959
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1331 (https://doi.org/10.1351/pac199567081307)
See alsoBenzynes; Dehydroarenes
Record as JSON
{
  "id": "MLC-T-CHM-002959",
  "term": "Dehydrobenzenes",
  "field": "Chemistry",
  "definition": "Reactive intermediates of formula C6H4 derived from benzene by formally removing two hydrogen atoms, named as didehydrobenzenes with locants. The 1,2-isomer is benzyne, with a formal triple bond, while 1,3- and 1,4-didehydrobenzene are separate species with no such bond, the latter being the intermediate of the Bergman cyclization. All are generated in situ and are too reactive to isolate under ordinary conditions.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "benzynes",
    "dehydroarenes"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1331 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/dehydrobenzenes/"
}

Record 3,147 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.