Donnan emf
Term · Chemistry · MLC-T-CHM-003381
The electromotive force (emf) that develops across a semipermeable membrane separating two electrolyte solutions, one of which contains a non-diffusible charged species. This potential arises from the unequal distribution of diffusible ions across the membrane at equilibrium. It is a consequence of the Donnan equilibrium and can be measured experimentally.
| Identifier | MLC-T-CHM-003381 |
|---|---|
| Field | Chemistry |
| Subject | Physical and Biophysical Chemistry |
| Synonyms | Donnan potential |
| References | PAC, 1972, 31, 577. 'Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry' on page 619 (https://doi.org/10.1351/pac197231040577) |
| See also | Donnan equilibrium; Electric current; Salt |
Record as JSON
{
"id": "MLC-T-CHM-003381",
"term": "Donnan emf",
"field": "Chemistry",
"definition": "The electromotive force (emf) that develops across a semipermeable membrane separating two electrolyte solutions, one of which contains a non-diffusible charged species. This potential arises from the unequal distribution of diffusible ions across the membrane at equilibrium. It is a consequence of the Donnan equilibrium and can be measured experimentally.",
"synonyms": [
"Donnan potential"
],
"subject": "Physical and Biophysical Chemistry",
"see_also": [
"Donnan equilibrium",
"electric current",
"salt"
],
"references": [
"PAC, 1972, 31, 577. 'Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry' on page 619 (https://doi.org/10.1351/pac197231040577)"
],
"url": "https://mlchart.com/terminology/chemistry/donnan-emf/"
}
Record 3,593 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.