MLchartDataset catalogue

Geminate pair

Term · Chemistry · MLC-T-CHM-004803

A pair of reactive species, such as radicals or ions, that are formed simultaneously in close proximity within a solvent cage. These species have a higher probability of reacting with each other than with other species in the bulk solution. The recombination of a geminate pair is often referred to as geminate recombination.

Table 1. Record
IdentifierMLC-T-CHM-004803
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1117 (https://doi.org/10.1351/pac199466051077)
See alsoCage; Electron transfer; Ion pair; Molecular entity; Radical pair
Record as JSON
{
  "id": "MLC-T-CHM-004803",
  "term": "Geminate pair",
  "field": "Chemistry",
  "definition": "A pair of reactive species, such as radicals or ions, that are formed simultaneously in close proximity within a solvent cage. These species have a higher probability of reacting with each other than with other species in the bulk solution. The recombination of a geminate pair is often referred to as geminate recombination.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "cage",
    "electron transfer",
    "ion pair",
    "molecular entity",
    "radical pair"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1117 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/geminate-pair/"
}

Record 5,087 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.