Gibbs energy diagram
Term · Chemistry · MLC-T-CHM-004876
A plot of the standard Gibbs energy of a system against a reaction coordinate, illustrating the energy profile of a chemical reaction. The diagram shows the relative Gibbs energy levels of reactants, transition states, reaction intermediates, and products. The highest point on the reaction path between two species corresponds to the transition state, and its energy difference from the reactants defines the Gibbs energy of activation.
| Identifier | MLC-T-CHM-004876 |
|---|---|
| Field | Chemistry |
| Subject | Physical and Biophysical Chemistry |
| Synonyms | energy profile; Gibbs energy profile; free energy profile |
| References | PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1117 (https://doi.org/10.1351/pac199466051077); PAC, 1996, 68, 149. 'A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)' on page 167 (https://doi.org/10.1351/pac199668010149) |
| See also | Gibbs energy; Bond order; Intermediate; Potential-energy profile; Potential-energy surface; Rate-determining step; Reaction coordinate; Sequence; Standard state; Stepwise reaction; Transition state |
Record as JSON
{
"id": "MLC-T-CHM-004876",
"term": "Gibbs energy diagram",
"field": "Chemistry",
"definition": "A plot of the standard Gibbs energy of a system against a reaction coordinate, illustrating the energy profile of a chemical reaction. The diagram shows the relative Gibbs energy levels of reactants, transition states, reaction intermediates, and products. The highest point on the reaction path between two species corresponds to the transition state, and its energy difference from the reactants defines the Gibbs energy of activation.",
"synonyms": [
"energy profile",
"Gibbs energy profile",
"free energy profile"
],
"subject": "Physical and Biophysical Chemistry",
"see_also": [
"Gibbs energy",
"bond order",
"intermediate",
"potential-energy profile",
"potential-energy surface",
"rate-determining step",
"reaction coordinate",
"sequence",
"standard state",
"stepwise reaction",
"transition state"
],
"references": [
"PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1117 (https://doi.org/10.1351/pac199466051077)",
"PAC, 1996, 68, 149. 'A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)' on page 167 (https://doi.org/10.1351/pac199668010149)"
],
"url": "https://mlchart.com/terminology/chemistry/gibbs-energy-diagram/"
}
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