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Imino carbenes

Term · Chemistry · MLC-T-CHM-005610

A carbene that carries an imino group, RN=, elsewhere in the molecule, as in R-C(:)-CH2-C(=NR)R, where the divalent carbon and the C=N unit are separate. The name is listed to warn against using it for alkylideneaminocarbenes, in which the nitrogen of the C=N unit is bonded directly to the carbene carbon.

Table 1. Record
IdentifierMLC-T-CHM-005610
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1343 (https://doi.org/10.1351/pac199567081307)
See alsoCarbenes; Nitrile ylides
Record as JSON
{
  "id": "MLC-T-CHM-005610",
  "term": "Imino carbenes",
  "field": "Chemistry",
  "definition": "A carbene that carries an imino group, RN=, elsewhere in the molecule, as in R-C(:)-CH2-C(=NR)R, where the divalent carbon and the C=N unit are separate. The name is listed to warn against using it for alkylideneaminocarbenes, in which the nitrogen of the C=N unit is bonded directly to the carbene carbon.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "carbenes",
    "nitrile ylides"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1343 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/imino-carbenes/"
}

Record 5,952 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.