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Indirect reaction

Term · Chemistry · MLC-T-CHM-005782

A reaction in which the colliding reactants form a reactive complex that lives longer than its period of rotation before breaking into products, also called a complex-mode reaction. Because the complex loses memory of the approach direction, the products in a molecular-beam experiment scatter at random with respect to the center of mass. It contrasts with a direct reaction, whose complex lives for less than one rotation and gives products scattered in preferred directions.

Table 1. Record
IdentifierMLC-T-CHM-005782
FieldChemistry
SubjectPhysical and Biophysical Chemistry
ReferencesPAC, 1996, 68, 149. 'A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)' on page 168 (https://doi.org/10.1351/pac199668010149)
See alsoComplex-mode reaction; Composite; Direct reaction; Lifetime; Molecular beams; Reactive complex
Record as JSON
{
  "id": "MLC-T-CHM-005782",
  "term": "Indirect reaction",
  "field": "Chemistry",
  "definition": "A reaction in which the colliding reactants form a reactive complex that lives longer than its period of rotation before breaking into products, also called a complex-mode reaction. Because the complex loses memory of the approach direction, the products in a molecular-beam experiment scatter at random with respect to the center of mass. It contrasts with a direct reaction, whose complex lives for less than one rotation and gives products scattered in preferred directions.",
  "subject": "Physical and Biophysical Chemistry",
  "see_also": [
    "complex-mode reaction",
    "composite",
    "direct reaction",
    "lifetime",
    "molecular beams",
    "reactive complex"
  ],
  "references": [
    "PAC, 1996, 68, 149. 'A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)' on page 168 (https://doi.org/10.1351/pac199668010149)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/indirect-reaction/"
}

Record 6,132 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.